The Reds' solitary defeat came against FC Basel in Switzerland last month, before the group phase concluded with Tuesday night's success.
The draw will start at 11am GMT, which is 12pm CET.
However, with a number of teams already qualified for the Champions League last 16 draw, many are asking when the draw for the knock-out stages will be.
The draw is being shown across the continent.
Their programme will begin at 11am GMT.
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The eight Champions League last-16 ties will take place over four days.
The dates are February 13/14 & 20/21 for the first-leg matches and March 6/7 & 13/14 for the second-legs. Sevilla can secure first place with a victory and Liverpool do not win. "These situations, apart from the frustration of not being in the next round, will help the team move forward and onto the Europa League", Simeone told beIN Sports Spain.
Only a freak set of results can stop Manchester United from reaching the knockouts.
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Lionel Messi was left on the bench at a sparsely populated Camp Nou as Paco Alcacer headed the hosts in front and Jeremy Mathieu then scored an own goal against his old side.
Liverpool welcome Spartak Moscow to Anfield on Wednesday knowing that they only need to avoid defeat to reach the last 16 for the first time in nine years.
Clubs from the same country can not play each other in the first knockout round.
Teams from the same group or country can not be drawn against one another.
Chelsea are two points ahead of Roma, but have an inferior head-to-head record against the Italian side who host Qarabag in their final fixture of the group.
Barcelona have not been at their free-flowing best for much of the season so far, but still lead La Liga by five points and eased into the last 16 as Group D winners.
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