For Peru, Jefferson Farfan and Renato Tapia are pushed to the bench, with Pedro Aquino coming in.
Mbappe's goal, which came from close-range after Olivier Giroud's shot took a wicked deflection to beat goalkeeper Pedro Gallese, saw the 19-year-old become the youngest player to score for France at a major worldwide tournament.
Some Peru fans were in tears even before kick-off - a generation of Peruvians have never known their country in the World Cup before.
Peru need to beat the strongly fancied French in Yekaterinburg in their Group C encounter or face an early exit from Russian Federation.
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Despite having secured a place in the final-16 after just two matches and two victories, France looked at best lethargic for the majority of the match.
Antoine Griezmann - who signed a new Atletico Madrid contract on Monday - had France's first opportunity in the 11th minute but Euro 2016's top scorer fired wide, while Paul Pogba also failed to work Peru goalkeeper Gallese.
But he stressed Peru, appearing at the World Cup for the first time in 36 years, would not be overawed.
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The first clear chance of the match was in the 31st minute with Paolo Guerrero's shot blocked by Hugo Lloris on his 100th appearance for France.
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66' Advincula strikes now, from the near corner of the 18 yard box.
Ricardo Gareca's side fell 1-0 loss to Denmark in the opening round of group play, in which the Danes clinched with a lone goal in the 59th minute.
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But France's early intensity started to fade and Peru should have taken advantage, yet Guerrero shot straight at Lloris on the turn after Christian Cueva found him in the box.