Murray's decision came after he won a trio of three-setters at the USA tournament and was a victim of a schedule that had him start his latest victory at midnight.
Citi Open tournament director Keely O'Brien said: "I am so grateful that Andy, an incredible champion, came back to DC to begin what we all know will be a great comeback".
The three-time major champion, coming back from hip surgery, finished his most recent match at 3 a.m. Friday and chose to withdraw rather than play again so soon afterward. It's not good for fans, TV.
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I don't think I should be put in a position like that.
Next up for Alex will be Japanese seventh seed Kei Nishikori, who dispatched Canadian ninth seed Denis Shapovalov 7-6 (1), 6-3. "Nobody", said Murray, a former No. 1 who had an operation on his right hip in January.
The 31-year-old Scotsman won his third three-set victory in four days, having been on the court for eight hours 11 minutes in all, and he started at midnight thanks to a fourth day of rain delays. "I don't know how players are expected to recover from that", Murray said. "I don't think it's reasonable", Murray said.
If his body can take it, Murray plays for a semifinal spot in Friday's last match against 72ndranked De Minaur, who pulled two upsets on Thursday after rain, dumping United States 11th seed Steve Johnson 6-4 7-5 and South Korean eighth seed Chung Hyeon 6-2 4-6 6-2.
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When nurses realized that the two gentlemen were missing, they called the local authorities to help them locate the escapees. Sure, it wasn't the outcome they were hoping for, but getting a police escort back to a nursing home is pretty badarse.
"I do understand 3 a.m.is very hard for everyone", O'Brien said.
Storms earlier in the week forced some men to play twice in one day.
The week in Washington saw Murray play the most consecutive matches since returning from the hip problem which kept him out for 11 months and he will now have a week's rest and recovery instead of heading to Canada. Wishing you a speedy recovery.
Murray looked set to win the opening set against Copil, ranked 93, after moving 5-0 ahead in the tie-break only for the Romanian to reel off seven points in a row. After the Round of 16 match, Murray sat in his chair and cried into a towel, according to The Washington Post.
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Alderweireld, 29, has plied his professional trade in England since 2014 following a transfer from Atletico Madrid. Tottenham chairman Daniel Levy is demanding £60million for the centre-back, who is desperately wanted by United.
"Just the emotions coming out at the end of an extremely long day", Murray said, "and a long match".